Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]

Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ3S,S′:S′;2:1κ3S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ2S,S′)cadmium]

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In the pale pink sns centrosymmetric title compound, [Cd2(C13H12NOS2)4], pairs of dithiocarbamate ligands exhibit different structural functions.Each of the terminal ligands is bidentately coordinated to one CdII atom and forms a planar four-membered CS2Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring CdII atoms, forming extended eight-membered C2S4Cd2 tricyclic units whose geometry can be approximated by a chair conformation.The coordination polyhedron of the CdII atoms is a distorted square-pyramid.The five-membered furan ring and the benzene ring are disordered over two sets of mako shark toys sites with an occupancy ratio of 0.62 (8):0.

38 (8).